Evaluation of rheological parameters of cordierite suspensions

Document Type : Research Article

/amnc.2017.6.22.3

Abstract

In this paper slip casting forming method for cordierite glass ceramic was investigated. Oxide raw materials and three dispersants were used for desirable suspension preparation. Raw materials processing (mixing and clcination, mixing and fritizing), milling time (both for wet and dry milling) and the dispersants percentages are the examined parameters in order to choose the stability conditions. Evaluation of the prepared suspensions were done using rheology, particle size distribution, zeta potential, slip casting rate and sedimentation tests. Results show that Dolapix PCN can be introduced as the most suitable dispersants for suspension preparation. The behavior of the suspensions were shear thinning at low shear rates and shear thickening at high shear rates. The stability of the suspension which was prepared by frit and the green density of its forming article were higher rather than the other suspensions.

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[1] James F Shackelford, Young-Hwan Han, Sukyoung Kim, Se-Hun Kwon, CRC materials science and engineering handbook: CRC Press, NewYork, 2010, 339-419.
[2] Camerucci M, Urretavizcaya G, Castro M, Cavalieri A, Electrical properties and thermal expansion of cordierite and cordierite-mullite materials, Journal of the European Ceramic Society, 21, 2001, 2917-2923.
[3] Zanotto E D, A bright future for glass-ceramics, American Ceramic Society Bulletin, 89, 2010, 19-27.
[4] Camerucci M A, Cavalieri A L, Moreno R, Slip casting of cordierite and cordierite– mullite materials, Journal of the European Ceramic Society, 18, 1998, 2149-2157.
[5] Rodrigues Neto J B, Moreno R, Rheological behaviour of kaolin/talc/alumina suspensions for manufacturing cordierite foams, Applied Clay Science, 37, 2007, 157-166.
[6] Rodrigues Neto J B, Moreno R, Effect of mechanical activation on the rheology and casting performance of kaolin/talc/alumina suspensions for manufacturing dense cordierite bodies, Applied Clay Science, 38, 2008, 209-218.
[7] Kobayashi Y, Sumi K, Kato E, Preparation of dense cordierite ceramics from magnesium compounds and kaolinite without additives, Ceramics International, 26, 2000, 739-743.
[8] Duncan Shaw, Introduction to colloid and surface chemistry, Elsevier Science, NewYork, 2003, 210-241.
[9] James S. Reed, Principles of ceramics processing, Wiley, USA, 1995, 260-293.
[10] R.P. Chhabra, J.F. Richardson, Non-newtonian flow and applied rheology, Oxford, Hungary, 2008, 1-55.
[11] J. George, Y. Onoda, The rheology of organic binder solutions, Ceramic processing before firing, Wiley, Netherlands, 1978, 235-251.
]12[ دیوید گسکل، سعیدرضا زارع و علیرضا اعلائی (مترجم)، آشنایی با پدیده­های انتقال در مهندسی مواد )سیالات، حرارت، نفوذ(، ارکان دانش، 1380.
[13] J W Goodwin, R W Hughes, Rheology for Chemists: an Introduction, Royal Society of Chemistry, Springer, UK, 2002.
[14] Muhammad N. Rahaman, Ceramic Processing and Sintering, CRC Press, NewYork, 2003, 181-248.