Study on photovoltaic properties of dye-sensitized solar cells based on indigo dyes in the presence of an anti-aggregation agent

Document Type : Research Article

Authors

1 Department of Organic Colorants, Institute for Color Science and Technology, Tehran

2 Center of Excellence of Color Science and Technology, Institute for Color Science and Technology, Tehran/ Department of Polymer Engineering and Color Technology, Amirkabir University of Technology, Tehran.

3 Department of Organic Colorants, Institute for Color Science and Technology, Tehran/ Center of Excellence of Color Science and Technology, Institute for Color Science and Technology, Tehran

/amnc.2016.4.16.1

Abstract

Nanostructured dye sensitized solar cells (DSSCs) based on indigo dyes exhibit medium to high power
conversion efficiency. Such organic dye molecules easily experience aggregation. As aggregation takes
place in dye molecules, electron transfer process in dye-sensitized solar cell will be worsen. Therefore,
anti-aggregation agents are commonly added to organic solution in DSSCs. Spectrophotometric evaluations
of indigo dyes applied on a TiO2 substrate in the presence and absence of an anti-aggregation
agent were carried out in order to assess changes in the efficacy of dyes. The results show that addition
of anti-aggregation agent reduced undesired J aggregates. Finally, dye sensitized solar cells were fabricated
to determine the photovoltaic properties as well as the influence of anti-aggregation agents on
their performance.

Keywords


[1] O'Regan B, Grätzel M, A low cost, high efficiency solar cell based on dye-sensitized colloidal TiO2 films, Nature, 353, 1991, 737-40.
[2] Rama A, Selvaraj K, Hayase S, Molecular dynamics simulations on the aggregation behavior of indoline type organic dye molecules in dye-sensitized solar cells, J. Mol. Model., 18, 2012, 2099-2104.
[3] Borrmann T, Richardson M, The use of nanostructured calcium silicate in solar cells, ACS pub., Beryline, 2009, 78-80
[4] Groningen R, Fullerene based Organic Solar Cells, Timisoara pub., Romaine, 1978, 154-157.
[5] Park SS, Won Y, Choi YC, Kim JH. Molecular Design of Organic Dyes with Double Electron Acceptor for Dye-Sensitized Solar Cell, Energ Fuel, 23, 2009, 3732-3736.
[6] Petermann R, Tian M, Tatsuura S, Furuki M, Synthesis of new squaraine dyes for optical switches, DyesPigments, 57, 2003, 43–54.
[7] Nasr S, Liu D, Hotchandani S, Kamat P, Dye-capped semiconductor nanoclusters, excited state and photosensitization aspects of rhodamine 6G H-aggregation bound to SiO2 and SnO2 colloids, J. Phys. Chem., 100, 1996, 11054-11061.
[8] Ito S, Miura S, Uchida S, Takota M, Sumika K, Liska P, Comte P, Gratzel M, High conversion efficiency organic dye-sensitized solar cells with a novel indoline dye, Chem Comm, 2008, 5194-5196.
[9] Shlyk-Kerner O, Samish I, Kaftan D, Holland N, Sai PSM, Kless H, Protein flexibility acclimatizes photosynthetic energy conversion to the ambient temperature, Nature, 442, 2006, 827-830.
[10] Nojiri M, Koteishi H, Nakagami T, Kobayashi K, Inove T, Yamaguchi K, Suzuki S, Structural basis of inter-protein electron transfer for nitrite reduction in denitrification, Nature, 462, 2009, 117-120.
[11] Hosseinnezhad M, Gharanjig K, Moradian S, The Synthesis of Organic Dye for Nanostructure Dye Solar Cell, The 22nd Iranian Seminar of Organic Chemistry, 19-21 August 2014.
[12] a) Hosseinnezhad M, Gharanjig K, Moradian S, The synthesis and application of a new disperse dye based on indoline on polyesters, J. Color. Sci. Tech, 4, 2012, 43-49; b) Hosseinnezhad M, Moradian S, Gharanjig K, Synthesis and Characterization of Two New Organic Dyes for Dye-Sensitized Solar Cells, Synth Comm, 44, 2014, 779-787.
[13] Hallas G, Towns A D, Dyes derived from aminothiophenes, Dyes Pigment, 33, 1997, 319-336.
[14] Zhan W H, Wu WJ, Hua J, Jing Y H, Meng F S, Tian H, Photovoltaic properties of new cyanine-naphthalimide dyes, Tetrahedron Letter, 48, 2007, 2461-2468.
[15] Boschloo G, Hagfeldt A, Activation Energy of Electron Transport in Dye-Sensitized TiO2 Solar Cells, J Phys Chem B, 109, 2005, 12093-12098.
[16] Ashokkumar R, Kathiravan A, Ramamurthy P, Aggregation behaviour and electron injection/ recombination dynamics of symmetrical and unsymmetrical Zn-phthalocyanines on TiO2 film, Phys Chem Chem Phys, 16, 2014, 1015-1021.
[17] Yum J, Jang R, Humphry-Baker R, Gratzel M, Cid J, Torres T, Nazeeruddin M, Effect of Coadsorbent on the Photovoltaic Performance of Zinc Pthalocyanine-Sensitized Solar Cells, Langmuir, 24, 2004, 5636-5640.