Viscosity stabilization of Nano-Composites of PVC Plastisol in underbody coating on (PVC/Closite-30B/ZnO)

Document Type : Research Article

Authors

1 Islamic Azad University of Yadegar-e-Emam, P.O.Box: 18735/334, Tehran, Iran

2 Chemical Engineering Department, Amirkabir University of Technology, P.O.Box: 15875/413, Tehran, Iran

AMNC.2017.5.19.6

Abstract

In this study, stabilization of plastisol of automotive underbody coating containing 1%, 3% and 5% of OMMT in the presence of Nano ZnO were prepared. Migration of plasticizer (DOP) used, in all of the samples before curing and aging were studied by incubation for 45 days. The best condition with minimum level of migration of the plasticizer was obtained for Nano composite containing 5% of Nano clay. Modification of thermal stability of the samples being another object of the present work were studied under similar curing conditions. Minimum thermal degradation was occurred with Nano composite containing 5% of Nano clay. Surface properties of Nano composite after aging for 6 months and curing of plastisols were studied by scanning electron microscopy (SEM). The comparison of pure Nano clay with Nano composites containing (1%, 3% and 5%) Nano clay were studied by X-Ray Diffraction (XRD).

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References

[1] Joanna pagacz; Krzysztof pie chowski, Dsc with stochastic at glass transition of PVC/MMT nano composites; J.Them. Anal. Calorim(2013) 111:1571-1575 Zheng X, Gilbert M. An investigation into the thermal stability ofPVC/montmorillonite
composites. J Vinyl Addit Technol. 2011;17:77–84.
[2] Dimitry OIH, Sayed WM, Mazroua AM, Saad ALG. Poly(vinylchloride)/nanoclay nanocomposites— electrical and mechanicalproperties. Polimery. 2009;54(1):8–14.
[3] Rodolfo A Jr, Innocentini Mei LH. Poly(vinyl chloride)/metallicoxides/organically modified montmorillonite100nm nanocomposites:fire and smoke behavior. J Appl Polym Sci. 2010;116:946–58.
[4] Madaleno L, Schjrˇdt-Thomsen J, Cruz Pinto J. Morphology,thermal and mechanical properties of PVC/MMT nanocompositesprepared by solution blending and solution blending ? meltcompounding. Compos Sci Technol. 2010;70:804–14
[5] Sterky K, Hjertberg T, Jacobsen H. Effect of montmorillonitetreatment on the thermal stability of poly(vinyl chloride) nanocomposites. Polym Degrad Stab. 2009;94:1564–70
[6] Peprnicek T, Duchet J, Kovarova L, Malac J, Gerard JF, SimonikJ. Poly(vinyl chloride)/ clay nanocomposites: X-ray diffraction,thermal and rheological behavior. Polym Degrad Stab. 2006;91:1855–60..
[7] Kiersnowski A, Trelin´ska-Wlaz´lak M, Gazin´ska M, Pigłowski J.X-ray scattering and calorimetric studies of organoclays obtainedby ion-exchange. Polimery.2011;56(9):671–5
[8] Mansoori Y. Arghia s.v. et al Free radical grafting of polyacry- montmorilonite, European Polymer Journal 46 (2010) 1844-1853
[9] Hassane B., Carole l. et al ., Rheology and gellation kinetics of PVC plastisols., Rheol. Acta. (2007) 46: 825-838.
[10] Yeh.J.M , Huang.H.Y, et al Siloxane- modified epoxy resin- clay nanocomposite coating dispersion approach , Surf. Coat. Technol, 200(2006), 2753-2763
[11] Bagherzadeh, M.R; Mahdavi, F., Preparation of epoxy-clay nanocomposite and investigation on its anti-corrosive behavior in epoxy coating. Pro. Org. Coat. 60(2007),117-120.

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