Effect of curing time on the protective performance of ecofriendly silane sol-gel coating on mild steel

Document Type : Research Article

Authors

1 Faculty of Material and Metallurgical Engineering, College of Engineering, University of Tehran

2 School of Metallurgy and Materials Engineering, College of Engineering, University of Tehran

3 Department of Surface Coatings & Corrosion, Institute for Color Science and Technology

/amnc.2017.6.22.2

Abstract

This paper intends to evaluate the effect of curing time on the protective function of ecofriendly silane sol-gel coating applied on mild steel. The sol-gel coatings composed of three precursors, namely TEOS, MTES and GPS, were cured at 150 °C for 15, 45 and 75 min. In order to study the corrosion of coated steels, several surface analysis and electrochemical techniques were used. The optimum curing time was determined using the results of electrochemical impedance spectroscopy and polarization measurements. Moreover, HRSEM and water contact angle data indicated the optimum crosslink density of coating cured during 45 min revealing the most effective barrier effect.

Keywords


[1]      Alinejad S, Naderi R, Mahdavian M., The effect of zinc cation on the anticorrosion behavior of an eco-friendly silane sol – gel coating applied on mild steel, Progress in Organic Coatings, 101, 2016, 142–148.
[2]      Alinejad S, Naderi R, Mahdavian M, Effect of inhibition synergism of zinc chloride and 2-mercaptobenzoxzole on protective performance of an ecofriendly silane coating on mild steel, Journal of Industrial and Engineering Chemistry, 48, 2017, 88–98.
[3]      Asadi N, Naderi R, Saremi M, Determination of optimum concentration of cloisite in an eco-friendly silane sol-gel fi lm to improve corrosion resistance of mild steel, Applied Clay Science, 95, 2014, 243–251.
[4]      Suegama P, De Melo H., Recco A, Tschiptschin A, Aoki I, Corrosion behavior of carbon steel protected with single and bi-layer of silane films filled with silica nanoparticles, Surface and Coatings Technology, 202, 2008, 2850–2858.
[5]      Castro Y, Duran A, Damborenea J, Conde A, Electrochemical behaviour of silica basic hybrid coatings deposited on stainless steel by dipping and EPD, Electrochimica Acta, 53, 2008, 6008–6017.
[6]      Chou T, Organic inorganic hybrid coatings for corrosion protection, Journal of Non Crystalline Solids, 290, 2001, 153–162.
[7]      Naderi R, Fedel M, Deflorian F, Poelman M, Olivier M, Synergistic effect of clay nanoparticles and cerium component on the corrosion behavior of eco-friendly silane sol-gel layer applied on pure aluminum, Surface and Coatings Technology, 224, 2013, 93–100.
[8]      Palanivel V, Huang Y, Van Ooij W, Effects of addition of corrosion inhibitors to silane films on the performance of AA2024-T3 in a 0.5 M NaCl solution, Progress in Organic Coatings, 53, 2005, 153–168.
[9]      Eichinger E, Osborne J, Van Cleave T, Hexavalent chromium elimination: An aerospace industry progress report, Metal Finishing, 95, 1997, 36–41.
[10]   Nadargi D, Rao A, Methyltriethoxysilane : New precursor for synthesizing silica aerogels, Journal of Alloys and Compounds, 467, 2009, 397–404.
[11]   Van Ooij W, Zhu D, Stacy M, Seth A, Mugada T, Gandhi J, Puomi P, Corrosion Protection Properties of Organofunctional Silanes — An Overview, Tsinghua Science & Technology, 10, 2005, 639-664.
[12]   Chaudhury M., Gentle T, Plueddemann P, Adhesion mechanism of polyvinyl chloride to silane primed metal surfaces, Journal of Adhesion Science and Technology, 4243, 2017, 29-38.
[13]   Quinet M, Neveu B, Moutarlier V, Audebert P, Ricq L, Corrosion protection of sol – gel coatings doped with an organic corrosion inhibitor : Chloranil, Progress in Organic Coatings, 58, 2007, 46–53.
[14]   Gandhi J, Metroke T, Eastman M, Van Ooij W, Apblett A, Effect of the Degree of Hydrolysis and Condensation of Bis- [ Triethoxysilylpropyl ] Tetrasulfi de on the Corrosion Protection of Coated Aluminum Alloy 2024-T3, Corrosion, 62, 2006, 612–623.
[15]   Suegama H, Aoki I, Montemor M, Palomino M, Electrochemical study of modified non-functional bis-silane layers on Al alloy 2024-T3, Corrosion Science, 50, 2008, 1258–1266.
[16]   Suegama P, Recco A, Tschiptschin A, Aoki I, Influence of silica nanoparticles added to an organosilane film on carbon steel electrochemical and tribological behaviour, Progress in Organic Coatings, 60, 2007, 90–98.
[17]   Deflorian F, Rossi S, Fedel M, Motte C, Electrochemical investigation of high-performance silane sol – gel films containing clay nanoparticles, Progress in Organic Coatings, 69, 2010, 158–166.
[18]   Franquet A., Terryn H., Vereecken J, IRSE study on effect of thermal curing on the chemistry and thickness of organosilane films coated on aluminium, Applied Surface Science, 211, 2003, 259–269.
[19]   Phanasgaonkar A, Raja V, Influence of curing temperature , silica nanoparticles- and cerium on surface morphology and corrosion behaviour of hybrid silane coatings on mild steel, Surface and Coatings Technology, 203, 2009, 2260–2271.
[20]   Rafiaei F, Naderi R, Dehghanian C, Impact of curing on the corrosion performance of an eco-friendly silane sol – gel coating on 304L, RSC Advances, 2015, 43225–43233.
[21]  Asadi N, Naderi R, Saremi M,, Effect of curing conditions on the protective    performance of an ecofriendly hybrid silane sol-gel coating with clay nanoparticles applied on mild steel, Industrial and Engineering Chemistry Research, 53, 2014, 10644–10652.
[22] Bierwagen G, Reflections on corrosion control by organic coatings, Progress in Organic Coatings, 28, 1996, 43-48.