Preparation and characterization of polyaniline-cobalt ferrite nanocomposite applicable as a microwave absorber coating

Document Type : Research Article

Authors

1 Department of Physics, University of Arak, Arak, Iran

2 2Department of Physics, University of Arak, Arak و Iran

3 Department of Science, Arak University of Technology, Arak, Iran

4 Young Researchers and Elite Club, Arak Branch, Islamic Azad University, Arak, Iran

amnc.2017.5.18.7

Abstract

 In this restructure CoFe2O4 nanoparticles were first synthesized via precipitation method by various natural capping agents such as lactose, glucose and sucrose. Then CoFe2O4 / poly aniline nanocomposites then were prepared using an easy polymerization method in low temperature for surface coating of military equipment (invisible they radars) for microwave absorber and obviation it. The prepared products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and Fourier transform infrared (FT-IR) spectroscopy. Magnetic property studies of the products were carried out using an alternating gradient force magnetometer (AGFM) and the results illustrated super- paramagnetic behavior of CoFe2O4 nanoparticles.

Keywords


[1] Haibo Yang, Ting Ye, Ying L. in, Miao Liu, Excellent microwave absorption property of ternary composite: Polyaniline-BaFe12O19eCoFe2O4 powders, Journal of Alloys and Compounds 653 (2015) 135- 139.
[2] Poorbafrani. A, Kiani. E., Enhanced microwave absorption properties in Cobalt-Zinc ferrite based nanocomposites, international Journal of Magnetism and Magnetic Materials, Electro Ceram, http://dx.doi.org/10.1016/j.jmmm.2016.04.046.
[3] .Oikonomou. A, Giannakopoulou. Litsardakis, G. Design, Fabrication And Characterization Of Hexagonal Ferrite Multi- Layer Microwave Absorber, international Journal of Magnetism and Magnetic Materials 316, (2007), E827-E830.
[4] Bueno. A, Gregori. M., Nobrega M, Microwave Absorbing Properties of Ni0/5-Xzn0/5- Xme2xfe2o4 (Me = Cu, Mn, Mg) Ferrite-Wax Composite In X-Band Frequencies, Journal of Magnetism and Magnetic Materials 320, 2008, 864- 870.
[5]. Posner J.D, Engineered Nanomaterial: Where They Go, Nobody Knows, Nanotoday, 2009, 114– 115.
[6] Cojocariu A.M., Soroceanu M., Hrib L, Nica V, Caltun O.F., Mater Chemical Physics, 135, 2012, 728-
[7] Nikumbh n A.K, Pawar R.A, Nighot D.V, Gugale G.S, Sangale M.D Khanvilkar, M.B Nagawade, A.V., Superparamagnetic iron oxide/chitosan core/shells for hyperthermia application: Improved colloidal stability and biocompatibilityJournal of Magnetism and Magnetic Materials, 355, 2014, 22-30.
[8] Koseoglu Y, Alan F, Tan M, Yilgin R, Ozturk M, Low temperature hydrothermal synthesis and characterization of Mn doped cobalt ferrite nanoparticles Journal of Ceramics International, 38, 2012, 3625- 3634.

[9] Ding Z., Wang W., Zhang Y., Li F., Ping Liu J., Synthesis, characterization and adsorption capability for Congo red of CoFe2O4 ferrite nanoparticles Journal of Alloys and Compounds , 640, 2015, 362- 370.

 
[10] Kooti M., Afshari M., Magnetic cobalt ferrite nanoparticles as an efficient catalyst for oxidation of alkenes, Journal of Scientia Iranica F, 19, 2012, 1991- 1995.
 
[11] Reddy C.V, Byon C, Narendra B, Baskar D, Srinivas G, Shim J, Prabhakar Vattikuti S.V, Journal of Superlattices and Microstructures, 82, 2015, 165173.
 
 [12] Ali M.B, Maalam K.E, Moussaoui H.E, Mounkachi O, Hamedoun M, Masrour R, Hlil E.K and Benyoussef A., Effect of zinc concentration on the structural and magnetic properties of mixed Co–Zn ferrites nanoparticles synthesized by Sol/Gel method, Journal of Magnetism and Magnetic Materials, http://dx.doi.org/10.1016/j.jmmm.08.097.2015
[13] Huixia.n F, Baiyi C, Deyi Z, Jianqiang Z, Lin T, Preparation and characterization of the cobalt ferrite nano-particles by reverse coprecipitationJournal of Magnetism and Magnetic Materials 356, 2014, 68– 72.
[14] Kumar P. A, Chakraborty S, Ray M, Removal and recovery of Chromium from wastewater using short chain polyaniline synthesized on jute fiber, International Journal of Chemical Engineering, 141, 2008, 130-140.
[15] Kaner R. B, MacDiramrid A.G, Plastics that conduct electricity, International Journal of Apply. Polymer. Science, 258, 1988, 106-111.
[16] MacDiarmid A.G, Yang L.S, Huang W.S, Humphrey B.D, Polyaniline: Electrochemistry and application to rechargeable batteries, International Journal Synthesis Metal, 18, 1987 393-398.
[17] Wang J, To C.O, Zhou D, Wallace G.G, Novel electrode substrates for rechargeable lithium/ polypyrrole batteries, International Journal Power Sources, 140, 2005 162- 167.
[18] Mirmohseni A, Solhjo R, Preparation and characterization of aqueous polyaniline battery using a modified polyaniline electrode, International Journal of Eur. Polymer, 39, 2003 219- 223.
[19] Mirmohseni A, Oladegaragoze A, Detection and determination of Cr (VI) in solution using polyaniline modified quartz crystal electrode, International Journal of Apply Polymer. Science, 85, 2002, 2772- 2780.
[20] Ram M.K, Yavuz O, Lahsangah V., Aldissi, M, CO gas sensing from ultrathin nano-composite conducting polymer film, International Journal of Sensor. Actuators B Chemical, 106, 2005 750- 757.
[21] Anderson M.R, Mattes B.R, Reiss H, Kaner R.B, Conjugated polymer films for gas separations International Journal of Science, 252, 1991 1412- 1414.
[22] Kuwabata S, Martin C.R, (), Investigation of the Gas-transport properties of polyaniline,
International Journal of Membrane Science, 91, 1994, 1- 12.
[23] Armes S.P, Gottesfeld S, Beery J.G, Garzon F, Agnew S.F, Conducting polymer-colloidal
silica composites, Journal of Polymer, 32, 1991, 2325- 2330.
[24] Ohtani A, Abe M, Ezoe M, Doi T, Miyata T, Miyake A, Synthesis and properties of high molecular weight soluble polyaniline and its application to the 4MB-capacity barium ferrite floppy disks antistatic coating, Synthesis Metal, 57, 1993, 3696- 3701.
[25] Schoch K.F, Byers W. A, Buckley L. J, Deposition and characterization of conducting polymer thin films on insulating substrates, Journal of Synthesis. Metal, 72, 1995 13-23.