Evaluation of rheological properties and shear strength of modified plastisol by nano-silica and nano-calcium carbonate using Taguchi method

Document Type : Research Article

Authors
1 Polymer Engineering Group, South Tehran Branch, Islamic Azad University
2 Department of Polymer Engineering, South Tehran Branch, Islamic Azad University.
3 Department of Polymer Eng, Shiraz Branch, Islamic Azad University
amnc.2022.10.40.2
Abstract
Plastisol is a suspension of small poly(vinyl chloride) particles, plasticizer, stabilizer, pigment and filler and can be used as a coating for the underbody insulator of cars. In this study, the influence of additives and fillers on the rheological and mechanical properties of plastisol were evaluated by Taguchi experimental design method, taking into account that the type and amount of PVC resin and plasticizer remained unchanged. The type of calcium carbonate and the amounts of nano-silica, solvent and liquid additive were investigated as the factors at three levels and the L9 array was used in the Taguchi design of experiment. Low and high-speed viscosities, the Bingham viscosity and the yield strength of the samples, as well as their shear resistance (shear strength) were measured. Nano-calcium carbonate increases the yield strength, Bingham viscosity and improves the flow of plastisol. The influence of liquid additive is better than that of nano-silica powder in improving the properties of plastisol. The solvent decreases the Bingham viscosity while having little effect on the yield strength of the plastisol. Nano-silica and nano-calcium carbonate have a great effect on the shear strength of plastisol and increase the shear strength.
Keywords

  1. Y. Abdesselam, J.F. Agassant, R. Castellani, R. Valette, Y. Demay, D. GourdinR. Peres, Rheology of plastisol formulations for coating applications. Polymer Engineering & Science. 57(2017), 982-988.
  2. G. Rybachuk, I. Kozlova, V. MozzhukhinV. Guzeev, PVC plastisols: Preparation, properties, and application. Polymer Science Series C. 49(2007), 6-12.
  3. B. EftekhariM. Pishvaei, A Review on the Poly (Vinyl Chloride) Plastisol Coatings and Its Rheology. Journal of Studies in Color World. 10(2020), 13-28.
  4. H.A. Barnes, The yield stress—a review or ‘παντα ρει’—everything flows? Journal of Non-Newtonian Fluid Mechanics. 81(1999), 133-178.
  5. C. LaineP. Cassagnau, Prediction of zero shear viscosity of poly (vinyl chloride) plastisols. Applied Rheology. 16(2006), 136-144.
  6. M. RasteiroE. Antunes, Correlating the rheology of PVC-based pastes with particle characteristics. Particulate science and technology. 23(2005), 361-375.
  7. Y. Ji, G. Xu, Z. Yang, H. LuoH. Tan, Study on viscosity and aging process of CaCO3 filled poly (vinyl chloride) plastisols. Journal of Vinyl and Additive Technology. 24(2018), E53-E61.
  8. I. Bonadies, M. Avella, R. Avolio, C. Carfagna, M.E. ErricoG. Gentile, Poly (vinyl chloride)/CaCO3 nanocomposites: Influence of surface treatments on the properties. Journal of Applied Polymer Science. 122(2011), 3590-3598.
  9. Y. Lin, C.-M. Chan, Calcium carbonate nanocomposites, in Advances in polymer nanocomposites, Types and applications, F. Gao, Editor. Woodhead Publishing, Oxford. 2012, 55-90.
  10. A. JohansenT. Schæfer, Effects of interactions between powder particle size and binder viscosity on agglomerate growth mechanisms in a high shear mixer. European Journal of Pharmaceutical Sciences. 12(2001), 297-309.
  11. M. Fasihi, R. ArabzadehM. Moghbeli, Effect of silica particles on adhesion strength of polyvinyl chloride coatings on metal substrates. Iranian Journal of Chemical Engineering (IJChE). 14(2017), 74-82.
  12. ر قاسمی هجران دوست، م.ر. کلائی، د. زارعی، ارزیابی اثر پارامترهای مؤثر بر خواص رئولوژیکی و مکانیکی پوشش‌های خودروی پلاستیزول تقویت شده با نانوذرات سیلیکا با استفاده از روش تاگوچی. نشریه علمی پژوهشی مواد پیشرفته پوششهای نوین-27(1397)،1936-1925
  13. D. Wu, X. Wang, Y. SongR. Jin, Nanocomposites of poly (vinyl chloride) and nanometric calcium carbonate particles: Effects of chlorinated polyethylene on mechanical properties, morphology, and rheology. Journal of Applied Polymer Science. 92(2004), 2714-2723.