Physical, Mechanical and Thermal Properties of Epoxy Coatings Modified with Nitrile-Butadiene Nano-rubber

Document Type : Research Article

Authors

1 Polymer Eng, Islamic azad University, South Tehran Branch.

2 Department of Polymer Engineering, South Tehran Branch, Islamic Azad University.

3 nanotechnology Institute, Amirkabir university technology, Tehran, Iran

/amnc.2019.7.28.7

Abstract

The main purpose of this work is to study the physical, mechanical and thermal properties of epoxy based resin modified with acrylonitrile-butadiene-rubber (NBR) nanoparticles. At first, elastomer nanoparticle (ENP) at different content was added to epoxy resin. Then, the morphology of nanocomposite and dispersion condition of elastomer nanoparticles was studied using microscopy techniques including SEM, TEM and AFM.The results showed an acceptable dispersion condition for ENPs in epoxy resin. The tensile and impact strength of nanocomposites as two key parameters were thoroughly investigated. The results depicted two times increase in the amount of toughness besides three times increase in the amount of elongation at break in nanocomposite containing 1.5wt% of ENP. Thereafter, the specific coating experimnets including adhesion, hardness, impact, bending and water absorption were performed. The adhesion increased and water uptake was reduced while the toughness was enhanced. The best results were obtained in samples containing 1 wt% elastomeric nanoparticles.

Keywords

Main Subjects


[1] S. Khoee , A.R. Mahdavian , W.Bairamy, M. Ashjari, An investigation into the improvement of adhesive strength of polyimides by incorporation of elastomeric nanoparticles. J Colloid Interf Sci. 336 (2009) 872–878.
[2] W. Dong, Y.Liu, X. Zhang, J. Gao, F.Huang, Zh.Song, B. Tan, J.Qiao, Preparation of High Barrier and Exfoliated-Type Nylon-6/Ultrafine Full-Vulcanized Powdered Rubber/Clay Nanocomposites .Macromol. 38(2005) 4551-4553.
[3] M.E. Trevin˜ o-Martı´nez, Y. del Angel-Vargas, L.F. Ramos-de Valle, R.G. Lo´ pez-Campos, Synthesis of Elastomeric Nanoparticles via Microemulsion Polymerization. J Vinyl Addit Techn. 11(2005) 132-134.
[4] M. Rezaei Abadchi, A.Jalali-Arani, Synergistic effects of nano-scale polybutadiene rubber powder (PBRP) and nanoclay on the structure, dynamic mechanical and thermal properties of polypropylene (PP), Iran Polym J, 24 (2015), 805-813.
[5] Yi. Li, Bo Yin, M. Yang J. Feng, Effect of Ultrafine Full-Vulcanized Powdered Rubber on the Properties of the Intumescent Fire Retardant Polypropylene. J Macromol Sci. 49(2010) 143–154.
[6] Q. Wang, X. Zhang, S. Liu, H. Guia, J. Lai, Y. Liu, J.Gao, F. Huang, Zh. Song, B. Tan, J.Qiao, Ultrafine full-vulcanized powdered rubbers/PVC compounds with higher toughness and higher heat resistance. Polym. 46 (2005) 10614–10617.
[7] X.Ding, R. Xu, D. Yu, H. Chen, R.Fan, Effect of Ultrafine, Fully Vulcanized Acrylate Powdered Rubber on the Mechanical Properties and Crystallization Behavior of Nylon 6, J Appl Polym Sci. 90 (2003) 3503–3511.
[8] T. Saleesung, P. Saeoui, C. Sirisinh, Mechanical and thermal properties of thermoplastic elastomer based on low density polyethylene and ultra-fine fully-vulcanized acrylonitrile butadiene rubber powder (UFNBRP).Polym Test. 29 (2010) 977–983.
[9] P. SAE-OUI, CH.SIRISINHA, W.INTIYA, P. THAPTONG, Properties of Natural Rubber Filled with Ultrafine Carboxylic Acrylonitrile Butadiene Rubber Powder, Adv. Polym. Tech . 30(2011) 183–190.
[10] H. Ma, G. Wei, Y. Liu, X. Zhang, J. Gao, F. Huang, B.Tan , Zh. Song, J. Qi, Effect of elastomeric nanoparticles on properties of phenolic resin. Polym. 46 (2005) 10568–10573.
[11] N. Petchwattanaa, S.Covavisaruchb , N. Euapanthasate, Utilization of ultrafine acrylate rubber particles as a toughening agent for poly(lactic acid). Mater Sci Eng. 532 (2012) 64– 70.
[12] B. Ellis, Chemistry and Technology of Epoxy Resins Chapman & Hall 1993.
[13] C. May, Epoxy Resins: Chemistry and Technology, Second Edition, Marcel Dekker, 1988.
[14] Henry Lee, K. Neville, LETTERS - "Book Review - Handbook of Epoxy Resins", Ind. Eng. Chem. 59( 1967) 16–17.
[15] D.MicheliC.ApolloR.PastoreM.Marchet, X-Band microwave characterization of carbon-based nanocomposite material, absorption capability comparison and RAS design simulation,Compos Sci Technol. 70 ( 2010) 400-409.
[16] P.L.TehaM.MariattiaH.M.AkilaC.K.YeohaK.N.SeetharamubA.N.R.WagimancK.S.Behc, The properties of epoxy resin coated silica fillers composites. Mater Lett. (2007) 2156-2158.
[17] F. Huang , Y.Liu Xiaohong, Zh. Genshuan, W. Jianming, G. Zhihai, S. Manli, Zh, Jinliang Qiao, Effect of Elastomeric Nanoparticles on Toughness and Heat Resistance of Epoxy Resins. Macromol Rapid Comm. 23( 2002) 786-790.
[18] S.Khoee, N.Hassani, Adhesion strength improvement of epoxy resin reinforced with nanoelastomeric copolymer. Mat.Sci Eng. 527 (2010) 6562–6567.
[19] ع. موذن، م.ر. کلایـی، م. خراسـانی، اثـ ر نانوسـیلیکا در افـزایش چسـبندگی چسبهای فشار حساس اکریلیکی بر روی سطح پلیپروپیلن آمایش شده بـ ا روش پلاسما در نقطه بهینه، نشریه علمـی پژوهشـی علـوم و فنـاوری رنـگ، (1395)10، 87-79.
[20] M.Golshani Nasab , M.R. Kalaee, Epoxy/graphene oxide/liquid polysulfide ternary nano-composites: rheological, thermal and mechanical, characterization. RSC Adv. 51 (2016) 45357-45368.